Multi-phase polymeric materials: structure, properties and interfacial phenomena

多相聚合物材料：结构、性能和界面现象

• 批准号: RGPIN-2017-06733
• 负责人: WoodAdams, Paula
• 金额: $ 2.4万
• 依托单位: Concordia University
• 依托单位国家: 加拿大
• 项目类别: Discovery Grants Program - Individual
• 财政年份: 2022
• 资助国家: 加拿大
• 起止时间: 2022-01-01 至 2023-12-31
• 项目状态: 已结题
• 来源: https://www.nserc-crsng.gc.ca/ase-oro/Details-Detailles_eng.asp?id=759712
• 关键词: Multi; phase; polymeric; materials; structure

My research program encompasses a broad range of polymers and multiphase systems emphasizing surface/interfacial structure and dynamic properties including crystallization behavior, rheology and diffusion. Polymers (or plastics) and multiphase polymeric systems are used in many products important to Canada's economy from automobiles and airplanes, to cell phones and even pharmaceuticals.Interfaces, between polymers and their environment and between different constituents in a multiphase polymeric material, play a significant role in end-use and processing behaviors. There is a lack of quantitative relations between (i) the molecular structure of polymers and their local structure/composition at interfaces and (ii) the local structure/composition at interfaces and the overall material properties. This is important because the overall material properties determine product quality and production rate limitations.The objective of my program is to provide theoretically sound, quantitative relations between structures and properties of multi-phase polymeric materials and their interfaces with a focus on issues important to industry such that manufacturers can improve quality and productivity. We will achieve this objective by performing carefully designed, rigorous experimental studies of materials that are intermediate in complexity between model and industrial systems. For the next 5 years I will focus on 2 cases: molecular fractionation under slipping flow conditions and diffusion in molten polymers and concentrated solutions. I plan to produce data that can be used to derive and validate mathematical models relating the material structure and properties.The results of this work will be important to manufacturers of plastic resins as well as those who produce products using plastics. The mathematical models that will be developed from our data will allow the design of materials with particular properties and will aid in trouble-shooting of polymer processing operations.

我的研究计划涵盖广泛的聚合物和多相系统，强调表面/界面结构和动态性能，包括结晶行为、流变学和扩散。聚合物（或塑料）和多相聚合物系统用于对加拿大经济至关重要的许多产品，从汽车和飞机，到手机，甚至药品。聚合物与其环境之间以及多相聚合物材料中不同成分之间的界面在最终使用和加工行为中起着重要作用。在（i）聚合物的分子结构和它们在界面处的局部结构/组成与（ii）在界面处的局部结构/组成和整体材料性质之间缺乏定量关系。这是很重要的，因为整体材料性能决定产品质量和生产率的限制。我的计划的目标是提供理论上健全的，定量的多相聚合物材料及其界面的结构和性能之间的关系，重点放在重要的工业问题，使制造商可以提高质量和生产率。我们将通过对复杂性介于模型和工业系统之间的材料进行精心设计、严格的实验研究来实现这一目标。 在接下来的5年里，我将专注于两种情况：滑动流动条件下的分子分馏和熔融聚合物和浓溶液中的扩散。我计划生成可用于导出和验证与材料结构和性能相关的数学模型的数据。这项工作的结果对塑料树脂制造商以及使用塑料生产产品的人都很重要。从我们的数据中开发的数学模型将允许设计具有特定性能的材料，并有助于聚合物加工操作的故障排除。