Palladium-catalyzed oxidative cross-coupling for the synthesis of α-amino ketones.
Palladium-catalyzed oxidative cross-coupling for the synthesis of α-amino ketones.
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DOI：
10.1039/c9ra06108h
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发表时间：
2019-10-07
期刊：
影响因子：
3.9
通讯作者：
Wang, Yan-Bin
中科院分区：
文献类型：
--
作者：
Wei, Xiao-Hong;Li, Zhen-Hua;Zhao, Lian-Biao;Zhang, Ping;Zhou, Han-Cheng;Wang, Yan-Bin
A novel oxidative cross-coupling reaction for the synthesis of α-aryl α-amino ketones in the presence of palladium catalysts using T+BF4− as an oxidant has been developed. This transformation was achieved by direct C–H oxidation of α-aminocarbonyl compounds and arylation. The mild reaction has a broad reaction scope and gives desired α-aryl α-amino ketones in moderate to excellent yields. A novel oxidative cross-coupling reaction for the synthesis of α-aryl α-amino ketones in the presence of palladium catalysts using T+BF4− as an oxidant has been developed.
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