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Experimental and Theoretical Investigations of Organic Reaction Rates and Mechanisms

Experimental and Theoretical Investigations of Organic Reaction Rates and Mechanisms
有机反应速率和机理的实验和理论研究
批准号:
8810457
负责人:
Robert Armstrong
金额:
$42.06万
依托单位国家:
美国
项目类别:
Continuing Grant
财政年份:
1989
资助国家:
美国
项目状态:
已结题
起止时间:
1989-01-15 至 1991-12-31

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中文摘要
翻译
这个项目是对有机分子反应的实验和理论研究的继续,目的是确定这些体系中键的形成时间,并发展基于过渡态分子轨道的周环反应的一般理论。基态扭曲与立体选择性的关系将通过计算和X射线结构测定来探讨。
英文摘要
This project is a continuation of experimental and theoretical studies of reactions of organic molecules in order to determine the timing of bond formation in these systems and to develop a general theory of reactivity in pericyclic reactions based upon transition-state molecular orbitals. The relationship of ground-state distortions to stereoselectivity will be probed by calculations and x-ray structure determinations.
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ITR Collaborative Research: Enabling Microscopic Simulators To Perform System-Level Analysis
Curriculum Revitalization in Chemical Engineering
JGOFS/SMP: Data-based Models of Food Web Structure and Export Flux
  • 批准号:
    0049009
  • 项目类别:
    Standard Grant
  • 资助金额:
    $33.77万
  • 财政年份:
    2000
  • 负责人:
    Robert Armstrong
  • 依托单位:
JGOFS/SMP: Data-based Models of Food Web Structure and Export Flux
  • 批准号:
    0001408
  • 项目类别:
    Standard Grant
  • 资助金额:
    $33.77万
  • 财政年份:
    2000
  • 负责人:
    Robert Armstrong
  • 依托单位:
海外基金