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Structural Studies of Large Complexes, Clusters and Radicals Using Rotational Coherence Spectroscopy

Structural Studies of Large Complexes, Clusters and Radicals Using Rotational Coherence Spectroscopy
使用旋转相干光谱对大型配合物、团簇和自由基进行结构研究
批准号:
9115656
负责人:
Peter Felker
金额:
$33.36万
依托单位国家:
美国
项目类别:
Continuing Grant
财政年份:
1991
资助国家:
美国
项目状态:
已结题
起止时间:
1991-12-01 至 1994-11-30

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中文摘要
翻译
在实验物理化学,化学 费尔克将利用旋转相干光谱学, 在超音速中获得大物种的几何结构 分子束这包括芳香族-芳香族化合物的研究, 二聚体和更高的集群,以及如何调查 氢键网络随簇大小而演变。 %%% 通过将气相分子暴露于短而尖锐的脉冲中 Felker教授(加州大学洛杉矶分校) 将获得关于一个小的, 控制相互作用分子的数量。该信息 这对于理解分子在 各种化学反应的初始阶段。
英文摘要
In this project in Experimental Physical Chemistry, Chemistry Division, Felker will use rotational coherence spectroscopy to obtain geometric structures of large species in supersonic molecular beams. This includes studies of aromatic-aromatic dimers and higher clusters, and investigations of how hydrogen-bonded networks evolve with cluster size. %%% By exposing molecules in the gas phase to short, sharp pulses of laser light at the proper frequency, Prof. Felker (UCLA) will obtain information about geometric structures of a small, controlled number of interacting molecules. This information is very useful for understanding how molecules behave in the initial stages of a wide variety of chemical reactions.
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Collaborative Research: Noncovalently Bound Molecular Trimers: High-dimensional and Fully Coupled Quantum Calculations of their Vibrational Levels
Nonlinear Raman Spectroscopy of Intermolecular Vibrations in Molecular Clusters
  • 批准号:
    9807372
  • 项目类别:
    Continuing Grant
  • 资助金额:
    $35.55万
  • 财政年份:
    1998
  • 负责人:
    Peter Felker
  • 依托单位:
Size-selective Spectroscopic Studies of the Geometries, Intermolecular Vibrations and Intermolecular Potential Energy Surfaces of Molecular Clusters
  • 批准号:
    9418349
  • 项目类别:
    Continuing Grant
  • 资助金额:
    $39.77万
  • 财政年份:
    1994
  • 负责人:
    Peter Felker
  • 依托单位:
High Resolution Studies of Jet-Cooled Large Molecules and Complexes Using Time-Domain and Interferometric Techniques
  • 批准号:
    8813470
  • 项目类别:
    Continuing Grant
  • 资助金额:
    $26.88万
  • 财政年份:
    1988
  • 负责人:
    Peter Felker
  • 依托单位:
海外基金