Synthesis and Characterization of Novel Frameworks and Their Inclusion Complexes

9413003 Parise这项工作的目标是使用基于有机模板的化学策略并通过改变反应条件来制备新型微孔硫代和硫氧化物骨架。该提案将探索阳离子交换作为框架改进剂的作用，旨在生产能够捕获和控制筛子释放气体的材料。具有规则间隔的孔和通道的开放晶体结构的合成和表征与化学分离、催化、离子交换和离子导电性等各种战略领域的工业具有高度的相关性。这类材料的精选成员在环境污染、炼油和健康科学的生物传感器等领域得到了应用。***

9413003 Parise The objective of this work is to make novel microporous thio and thio-oxide frameworks using chemical strategies based on organic templates and by varying the reaction conditions. The proposal will explore the role of cation exchanges as a framework modifier designed to produce materials capable of trapping and controlling the release of gases from sieves. %%% The synthesis and characterization of open crystalline structures possessing regularly spaced pores and channels are of high relevance to industry in strategic areas as varied as chemical separations, catalysis, ion exchange, and ion conductivity. Selected members of this class of materials find applications in areas such as environmental pollution, oil refining, and biosensors for the health sciences. ***