Lone Pairs, Hydrogen Bonds and Ionic Solvation

加州大学圣地亚哥分校的Perrin教授将继续研究非成键电子对对反应的影响，溶液中氢键的不对称性以及离子溶剂化对立体电子性质的影响。每一种都对反应速率和立体化学有细微但重要的影响。虽然是基础研究意义上的报道，但在有机、物理、理论和生物化学等领域具有广泛的意义。非键电子、氢键和离子溶剂化引起的微妙电子效应在生命过程和化学操作中具有重要影响。因此，本研究结果对基础科学和生命科学具有广泛的潜在影响。

Professor Perrin of the University of California San Diego will continue his investigations on the effects of nonbonding electron pairs, on reactions, the asymmetry of hydrogen bonds in solution and the effects of ion solvation on stereoelectronic properties. Each of these has subtle but significant effects on reaction rates and stereochemistry. While they are reported in the sense of basic research, the implications are of wide significance in organic, physical, theoretical and biochemistry. There are subtle electronic effects caused by nonbonded electrons, hydrogen bonds and solvation of ions which have significant consequences in life processes as well as chemical manipulations. Thus, the results of this investigation have broad spectrum potential impacting fundamental and life sciences.