RIMI: Conformational Studies Using Dynamic NMR Spectroscopy and Computational Methods

9450455拟议的研究将由两部分组成。第一部分是环丙基共轭的核磁共振研究，比较了三元环、双键和苯基的给电子能力。第二部分是利用核磁共振波谱和分子轨道计算对尿素、硫脲及其相关化合物的构象和成键的研究。这些项目将广泛使用核磁共振波谱和计算方法，并将为少数民族学生提供使用构象和结构分配方法的经验。

9450455 The proposed research would consist of two parts. The first part consists of NMR studies of cyclopropyl conjugation, for comparing the electron donating abilities of the three membered ring, double bond and phenyl group. The second part consists of a study of conformation and bonding in ureas, thioureas and related compounds using NMR spectroscopy and molecular orbits calculations. These projects will make extensive use of NMR spectroscopy and computational methods and will provide minority students with experience in using both methods of assigning conformation and structure.