Ionic Organic Reactions and their Intermediates

这项研究的重点包括三个具体领域。 一是 长寿命碳阳离子的研究将扩展到制备 用作Mukaiyama的不对称催化剂的手性碳阳离子 反应 第二，理论上的碳化和聚阳离子， 结构和合成兴趣将通过实验和 理论 第三，烷基阳离子的吉东原溶剂化， 和酰基阳离子和双阳离子，以及鎓离子将在 超强酸体系 有了这个更新奖，合成有机计划正在支持 乔治博士的研究1994年诺贝尔文学奖赢家奥拉· 化学，来自南方大学化学系 加州。 Olah博士继续把工作重点放在研究 有机离子及其反应。 理论研究，寻找 催化活性和制备反应将进行

The focus of this research includes three specific areas. First, the study of long-lived carbocations will be extended to the preparation of chiral carbocations for use as asymmetric catalysts for the Mukaiyama reaction. Second, Carbodications and polycations of theoretical, structural and synthetic interest will be studied by both experiment and theory. Third, gitonic protosolvation of alkyl cations, of carboxonium and acyl cations and dications, and of onium ions will be studied in superacidic systems. With this renewal award, the Synthetic Organic Program is supporting the research of Dr. George A. Olah, winner of the 1994 Nobel Prize in Chemistry, from the Department of Chemistry at the University of Southern California. Dr. Olah continues to focus his work on the study of organic ions and their reactions. Theoretical studies, the search for catalytic activity , and preparative reactions will be carried out