Pillared Layered Compounds: Their Synthesis, Structure and Properties

9707151克利尔菲尔德标题为“柱撑层状化合物：它们的合成、结构和性质”的提案的目的是合成和表征由层状化合物与无机聚合物和有机交联剂的柱撑作用获得的新材料. 四个领域强调：柱撑金属磷酸盐，有机柱撑磷酸盐，柱撑粘土和层状双氢氧化物。 大量的合成工作将与材料研究相结合，这些材料研究与结构测定、磁性测量、吸附和催化有关。 强调新材料的合成及其性能，以及层状化合物的操作以产生具有不寻常性能的多孔材料，例如层状化合物中的磁性现象的知识，将对材料化学的潜在功能材料的应用做出重大贡献，例如传感器，分子筛，分离介质和催化剂。 ***

9707151 Clearfield The aim of this proposal entitled Pillared Layered Compounds: Their Synthesis, Structure and Properties is to synthesize and characterize novel materials obtained from the pillaring of layered compounds both with inorganic polymers and organic cross- linking agents. Four areas are emphasized: pillared metal phosphates; organically pillared phosphates; pillared clays; and layered double hydroxides. A large amount of synthetic work will be carried out coupled with materials studies related to structure determination, magnetic measurements, and sorption and catalysis. %%% The emphasis on the synthesis of novel materials and their properties, and the manipulation of layered compounds to produce porous materials with unusual properties such as knowledge of magnetic phenomena in layered compounds, will result in significant contributions to materials chemistry of potentially functional materials for applications such as sensors, molecular sieves, separations media, and catalysts. ***