Synthesis, Structure and Properties of Open Framework Sulfides Coupled with Real-Time Synchrotron X-ray Powder Diffraction Studies

小行星9713375 将探索生产新型结晶微孔固体的策略，用于一类新的开放框架金属硫属化物材料。研究将集中在1）进一步开发用于生产开放框架的不寻常和传统的合成策略; 2）确定晶体结构; 3）实施用于真实的时间研究的小环境单元和其他原位装置，以帮助理解水热条件下的反应，测量真空和流动气体下的热稳定性，以及伴随离子交换、气体加载和嵌入的结构变化; 4）在同步辐射源下从微晶和粉末中收集数据和结构解的技术的发展; 5）稳定性、光学和离子交换性质的表征，以及这些与结构的相关性。 开放结构的金属硫族化合物代表了一类相对较新的材料，具有潜在的应用领域，如选择性吸附剂，离子交换剂，离子导体和包合物化学的主体。 ***

9713375 Parise Strategies to produce novel crystalline microporous solids will be explored for a new class of open framework metal chalcogenide materials. The research will focus on 1) further development of unusual and traditional synthetic strategies for the production of open frameworks; 2) determination of the crystal structures; 3) implementation of the small environmental cell for real time srudies and other in situ devices to aid in understanding reactions under hydrothermal conditions, measuring thermal stability under vacuum and flowing gas, and structural changes accompanying ion exchange, gas loading and intercalation; 4) development of techniques for data collection and structure solution from microcrystals and powders at synchrotron sources; 5) characterization of th estability, optical and ion exchange properties, and correlation of these with structure. %%% Open structured metal-chalcogenides represent a relatively new class of materials with potential areas of application such as selective sorbents, ion-exchangers, ion-conductors and hosts for inclusion chemistry. ***