Metalloporphyrin-Based Magnetic Materials

该奖项是由先进材料计划在化学 化学系与化学系固体化学专业 向犹他州大学提供材料研究支持 关于Joel S米勒。该研究将探索结构-功能 金属卟啉/四氰基乙烯（TCNE）基磁性材料 材料的目标是发现新的有机基磁体， 高临界温度、磁饱和力矩和环境温度 稳定研究重点将强调的作用是 卟啉配体周围的自旋，共价键的影响 成键和超分子氢键，新磁体的合成 基于TCNE以外的阴离子自由基受体， 卟啉与其他高自旋金属离子的光磁配合物 锰卟啉/TCNE复合物中的影响，以及压力 铁磁性对压力的依赖性。 协作物理 测量和计算研究将补充合成 研究的各个方面。 有机磁铁易于处理，并提供合成多样性 需要设计各种磁性材料， 可控特性这项研究将有助于确定 结构-性能关系 新一代的磁铁具有潜在的应用在电子 和光子器件。

This award is made by the Advanced Materials Program in the Chemistry Division and the Solid State Chemistry Program in the Division of Materials Research to the University of Utah in support of the research of Joel S. Miller. The research will explore structure- function relationships in metalloporphyrin/tetracyanoethylene(TCNE)-based magnetic materials with the goal of discovering new organic based magnets with high critical temperatures, magnetic saturation moments and ambient stability. Research thrusts which will be emphasized are the role of spins on the periphery of the porphyrin ligand, effect of covalent bonding and supramolecular hydrogen bonding, synthesis of new magnets based on anion-radical acceptors other than TCNE, synthesis of porphyrin complexes with other high spin metal ions, photomagnetic effects in manganese porphyrin/TCNE complexes, and the pressure dependence of ferromagnetism on pressure. Collaborative physical measurements and computational studies will supplement the synthetic aspects of the research. Organic based magnets are tractable and offer the synthetic diversity necessary to design a variety of magnetic materials with predictable and controllable properties. This research will help define structure-performance relationships for a new generation of magnets with potential applications in electronic and photonic devices.