MRI: Acquisition of CCD Single Crystal X-ray Diffractometer
MRI: Acquisition of CCD Single Crystal X-ray Diffractometer
批准号:
0116041
负责人:
Wiley Youngs
金额:
$20.45万
依托单位:
依托单位国家:
美国
项目类别:
Standard Grant
财政年份:
2001
资助国家:
美国
项目状态:
已结题
起止时间:
2001-08-15 至 2004-07-31
中文摘要
在主要研究仪器(MRI)项目的支持下,阿克伦大学化学系将获得一台带有CCD探测器的x射线衍射仪,用于单晶衍射。该设备将加强许多领域的研究,包括:a)环环和杂环化学;B)金属-硅基配合物;C)电子缺陷有机金属化合物的合成与表征;D)配位聚合物作为沸石类似物;e)树突大分子的制备、认识和利用。x射线衍射仪可以精确测量分子的完整三维结构,包括键的距离和角度,并提供分子相对于邻近分子的空间排列的准确信息。这些研究将在许多领域产生影响,包括制备更有效的催化剂和材料化学。
英文摘要
With support from the Major Research Instrumentation (MRI) Program, the Department of Chemistry at the University of Akron will acquire a X-ray diffractometer with CCD detector for single crystal diffractometry. This equipment will enhance research in a number of areas including the following: a) cyclyne and heterocyclyne chemistry; b) metal-silyl complexes; c) synthesis and characterization of electron deficient, organometallic compounds; d) coordination polymers as zeolite analogs; and e) the preparation, understanding and utilization of dendritic macromolecules.The X-ray diffractometer allows accurate and precise measurements of the full three dimensional structure of a molecule, including bond distances and angles, and it provides accurate information about the spatial arrangement of the molecule relative to the neighboring molecules. These studies will have an impact in a number of areas, including the preparation of more efficient catalysts and materials chemistry.
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Heterocyclynes
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批准号:0315980
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项目类别:Continuing Grant
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资助金额:$42.0万
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财政年份:2003
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负责人:Wiley Youngs
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依托单位:
Metallocyclotriynes
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批准号:9021093
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项目类别:Continuing Grant
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资助金额:$15.84万
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财政年份:1990
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负责人:Wiley Youngs
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依托单位:
海外基金