UNS: Collaborative Research: Testing the paradigms of the colloidal glass: Novel concentration jump experiments and large scale computer modeling

CBET - 1506072 McKenna，Gregory B.CBET - 1506079 Zia，Roseanna N.胶体是颗粒在液体（例如水）中的分散体，并且颗粒非常小，以至于它们在很长时间内不会分离。这些材料广泛用于油漆和油墨等商业产品。 它们也被认为是一种很好的眼镜模型材料。 目前的工作是一项合作研究，结合实验和大规模的计算机模拟，将提供新的科学认识的行为的胶体玻璃和比较将与知识的文献中有关的分子玻璃在类似的条件下。 研究生和高中生将参加这两个机构的研究活动。理解复杂物质中的动力学停驻是软物质科学的一个巨大挑战。大多数对胶体系统在堵塞附近的研究假设与分子玻璃中的相应行为相同。然而，最近的研究揭示了胶体中的非平衡响应，其与通过Kovacs签名监测的玻璃态动力学性质不同，即，本征等温线、接近的不对称性和记忆效应。拟议的研究将阐明这种差异的结构基础，通过一种新的实验和动态模拟相结合。结构和动力学将在类似于分子玻璃形成系统的Kovacs实验的实验中确定。在这里，刺激响应颗粒将以恒定的数量密度改变直径，以创造浓度跳跃条件，以模仿科瓦奇签名实验的温度跳跃。并行模拟将影响计算机模拟中的类似条件。实验和模拟将相互通知和验证，对干扰过渡附近的胶体动力学的联合询问将可能对软物质中的被捕状态产生变革性的理解。 从更广泛的意义上说，这是两个非常不同的PI的合作。 一个是分子玻璃实验物理学专家，特别是老化方面。另一位是大规模计算机模拟方面的专家，重点是胶体系统。结果提供了独特的跨学科的培训，研究生在计算和实验物理，加深他们的动力学和分子和胶体玻璃老化的基础知识。此外，妇女和代表性不足的少数民族将作为本科生和研究生研究人员发挥核心作用。

CBET - 1506072 McKenna, Gregory B.CBET - 1506079 Zia, Roseanna N.Colloids are dispersions of particles in a liquid, such as water, and the particles are so small that they do not separate for very long times. The materials are widely used in commercial products such as paints and inks. They are also believed to be a good model materials for glasses. The present work is a collaborative study that combines experiment and large scale computer simulations that will provide novel scientific understanding of the behavior of colloidal glasses and comparisons will be made with knowledge from the literature concerning molecular glasses in similar conditions. Graduate and high school students will participate in the research activities at both PIs' institutions.Understanding dynamical arrest in complex matter is a great challenge in soft matter science. Most study of colloidal systems near jamming assumes parity with corresponding behavior in molecular glasses. Yet, recent studies reveal non-equilibrium responses in colloids that differ qualitatively from glassy dynamics as monitored via the Kovacs signatures, viz., the intrinsic isotherm, the asymmetry of approach, and the memory effect. The proposed study will illuminate the structural underpinnings of such differences through a novel combination of experiment and dynamic simulation. The structure and dynamics will be determined in experiments analogous to the Kovacs experiments for molecular glass-forming systems. Here stimulus-responsive particles will change diameter at constant number density to create concentration-jump conditions to mimic the temperature-jumps of the Kovacs signature experiments. Concurrent simulations will effect similar conditions in silico. Experiment and simulation will inform and validate each other and the joint interrogation of the colloid dynamics near to the jamming transition will potentially create a transformative understanding of arrested states in soft matter. In a broader sense, this is a collaboration of two very different PIs. One is an expert in the experimental physics of molecular glasses, especially aging. The other is an expert in large scale computer simulation, with emphasis on colloidal systems. The result provides unique cross-disciplinary training to graduate students in both computational and experimental physics, deepening their knowledge of the fundamentals of dynamics and aging of molecular and colloidal glasses. Further, women and under-represented minorities will play a central role as undergraduate and graduate researchers.