Collaborative Research: Direct, Nozzle-Free Printing of Functional Nanomaterials Using Ultrasound Bubble Cavitation

该项目旨在为无喷嘴液体喷射系统工作机制背后的基础科学提供强有力的理解。广泛使用的最先进的印刷技术主要依赖于使用喷嘴来沉积材料。喷嘴可能会堵塞，这对打印可靠性和再现性产生不利影响。当高分辨率打印的喷嘴直径减小时，这个问题变得更加明显，这是越来越多的需求。此外，很难打印含有颗粒、薄片和高纵横比纳米材料的油墨或浆料。该奖项支持研究，为开发无喷嘴增材制造工艺提供知识，该工艺可以消除堵塞，并实现高分辨率打印所需的更窄的射流。超声气泡空化工艺可以在刚性和柔性基板上沉积不同类型、形状和尺寸的纳米材料。没有喷嘴消除了堵塞问题。基于纳米材料的增材制造设备有着广泛的应用，从电子到生物材料再到传感器。因此，本研究的结果对印刷业和国民经济都是有益的。本项目涉及应用物理、电气工程、机械工程、生物工程、材料科学等多个学科。多学科研究创造了一个独特的环境，有助于扩大妇女和代表性不足的群体在研究中的参与，并对工程教育产生积极影响。该项目利用YouTube和其他社交媒体平台向更广泛的社区传播知识。该项目研究了一种液体喷射系统，该系统由激光产生的聚焦超声产生的单个空化泡驱动，可以打印各种纳米结构。超声气泡空化打印过程是无喷嘴的，从而避免了现有的基于喷嘴的增材制造技术中的堵塞问题。然而，为了充分发挥该技术在增材制造中的应用潜力，需要对液体喷射和能量转换过程背后的基本机制有一个强有力的了解。为了了解超声波液体喷射机理，研究小组建立了气液界面和空化区的声学干扰模型，激光闪光阴影法捕获气泡形成和喷射的流体动力学，以及气泡形成动力学作为不同物理参数的函数。为了设计高效的光声换能器，该团队研究了激光参数对光吸收纳米复合材料热输运特性的影响，从而导致高压力幅值，研究了导致高焦增益的光声透镜的设计方面，并制造了复合透镜，并确定了几何增益，峰值压力幅值和透镜击穿因子。最后，该团队打印纳米材料薄膜，并将打印薄膜的质量和特性与传统打印系统获得的薄膜进行比较。该奖项反映了美国国家科学基金会的法定使命，并通过使用基金会的知识价值和更广泛的影响审查标准进行评估，被认为值得支持。

The project aims to provide a robust understanding of the fundamental science behind the working mechanism of a nozzle-free liquid-jetting system. Widely employed state-of-the-art printing techniques rely primarily on the use of nozzles to deposit materials. Nozzles can get clogged, which adversely affects printing reliability and reproducibility. This problem becomes more significant when the nozzle diameter is reduced for high-resolution printing, which is in increasing demand. Additionally, it is difficult to print inks or pastes that contain particles, flakes, and high-aspect ratio nanomaterials. This award supports research to provide knowledge for the development of a nozzle-free additive manufacturing process, which can eliminate clogs and enable narrower jet streams required for high resolution printing. The ultrasound bubble cavitation process enables deposition of different types, shapes, and sizes of nanomaterials on rigid and flexible substrates. The absence of nozzles eliminates clogging problems. Nanomaterial-based additively manufactured devices find a wide range of applications, from electronics to biomaterials to sensors. Therefore, the results from this study benefits the printing industry and the national economy. This project involves several disciplines including applied physics, electrical engineering, mechanical engineering, bioengineering, and materials science. The multi-disciplinary research creates a unique environment, which helps broaden participation of women and underrepresented groups in research and positively impacts engineering education. The project uses YouTube and other social media platforms to disseminate knowledge to a wider community.The project studies a liquid jetting system enabled by a single cavitation bubble created by laser-generated focused ultrasound to print various nanostructures. The ultrasound bubble cavitation printing process is nozzle-less, thus avoiding the clogging problems in existing nozzle-based additive manufacturing techniques. However, a robust understanding of the fundamental mechanism behind the liquid jetting and energy conversion processes involved is needed to realize the full application potential of using this technique for additive manufacturing. To understand the ultrasonic liquid jetting mechanism, the research team develops models of acoustic interference at the air-liquid interface and cavitation zone, laser-flash shadowgraphy to capture the hydrodynamics of bubble formation and jetting, and bubble formation dynamics as a function of varying physical parameters. To design efficient an optoacoustic transducer, the team studies the effect of laser parameters on thermal transport properties in light-absorbing nanocomposite materials leading to high pressure amplitudes, investigates design aspects of photoacoustic lens leading to high focal gain, and fabricates composite lenses and determines the geometric gain, peak pressure amplitude, and lens breakdown factors. Finally, the team prints nanomaterial films, and compares the quality and characteristics of printed films against those obtained with traditional printing systems.This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.