New Tellurium-Nitrogen pi-Heterocycles: Synthesis, Structure and Potential Applications as Molecular Magnets / Conductors

主要研究1,2,5-碲二唑环衍生物碲氮杂环的合成方法、分子结构、电子结构和化学性质，重点研究杂环还原成其自由基阴离子，并将其以热稳定盐的形式分离。同时对盐的磁性和电学性质进行实验和理论研究，以评估其作为设计和合成新功能材料-分子磁铁和/或导体的基础模块的潜力。

It is intended to perform fundamental research of methods for synthesis, molecular and electronic structure and chemical properties of tellurium-nitrogen heterocycles - derivatives of 1,2,5-telluradiazole ring system, with special emphasis on reduction of the heterocycles into their radical anions followed by isolation of the latter in the form of thermally stable salts, together with experimental and theoretical investigation of magnetic and electrical properties of the salts for evaluation of their potential as building blocks in the design and synthesis of new functional materials - molecular magnets and / or conductors.