Hybrid assemblies for fundamental studies of photo-induced multi-step charge transfer catalysis (C01)

这个跨学科的项目旨在控制混合组件中的多步电荷转移，用于电和光驱动的水的氧化。混合系统由用于分解水的分子催化剂组成，固定在氧化物吸收器膜上，该吸收器膜能够注入激发孔并为锚定提供足够的稳定性。进一步的工作集中于通过合适的锚定策略改善电荷转移，综合研究热极化子激发驱动的光化学活性，以及合作理论项目中的反应序列研究。

This interdisciplinary project aims to control multi-step charge transfer in hybrid assemblies for electrically and light driven oxidation of water. The hybrid systems consist of molecular catalysts for water splitting anchored to an oxide absorber film which is capable of injecting excited holes and offer sufficient stability for anchoring. Further work focusses on improved charge transfer by suitable anchoring strategies, the comprehensive study of photo-chemical activity driven by hot-polaron excitations as well as study of the reaction sequence in collaboration theory projects.