Formation and properties of opto-magnetic hybrid materials via the influence of external stimuli

复合系统可以允许性能的组合，不能或几乎没有发现均匀的化合物。为此，该项目应该将联合收割机配位聚合物或MOFs与纳米到微米级颗粒系统结合，用于合成复合系统。因此，它将扩大为两个具有各自专长的申请人的联合项目。目标复合材料应同时表现出光学和磁性，例如通过发光与超顺磁性的结合。为了实现这一目标，将研究不同的外部刺激以接触组件，除了第一个资助期的机械化学之外，还将包含其他机械相关的影响，例如喷雾干燥或声化学。普通的初步工作表明，发光MOF和磁性颗粒的组合可以产生非常有趣到令人惊讶的性质。特别是机械化学似乎有一个巨大的潜力，这两种材料类的组合。将研究不同组分、合成参数以及所得新混合物的结构和体系结构的影响，并确定物理性质。此外，该项目将尝试开发对核-壳结构的可控影响，从而根据MOF、颗粒系统、纳米颗粒类型和超颗粒结构以及合成条件的变化来控制核/壳与壳/核的顺序。总之，第一个资助期的结果将因此得到利用和进一步发展，以便对这种复合材料的形成进行概述，因为后者对于基础研究和应用（例如传感）都非常有趣。

Composite systems can allow for combinations of properties that cannot or hardly be found for homogenous compounds. For this purpose, the project is supposed to combine coordination polymers or MOFs with nano to microscale particle systems for the synthesis of composite systems. Therefore, it will be expanded to a joint project of two applicants of the respective expertise. The aimed-at composites shall exhibit simultaneous optical and magnetic properties, e.g. by combination of luminescence with superparamagnetism. In order to achieve this, different external stimuli will be investigated to contact the components, which –in addition to mechanochemistry of the first funding period- will also contain other mechano-related influences, such as spray drying or sonochemistry. Common preliminary work shows that highly interesting to surprising properties can result from the combination of luminescent MOFs and magnetic particles. Especially mechanochemistry seems to have an enormous potential for the combination of both material classes. The influence of different components, synthesis parameters as well as the resulting structure and architecture of the new hybrids will be investigated, and the physical properties determined. In addition, the project will attempt to develop controlled influencing of the core-shell architecture and thereby the sequence of core/shell vs. shell/core depending on variation of MOFs, particle systems, nanoparticle types and supraparticle architectures as well as the synthesis conditions. Altogether, the results of the first funding period will thereby be consequently utilized and further developed in order to get an overview on the formation of such composites, as the latter are both highly interesting for fundamental research as well as for applications, e.g. for in sensing.