Synthesis of novel porous coordination polymers from structured and functionalized ionic liquid media

我们提出了一个由离子液体合成新型多孔配位聚合物（金属有机骨架，MOF）的研究项目。离子液体具有三重作用。它用作MOF合成的前体、模板和溶剂。在第二个供资期，重点将放在模板效应上。为此，我们将重点研究液晶和手性离子液体的合成。将表征所得的新MOF材料，并将评估IL的结构变化与MOF的结构之间的关系。此外，我们希望优化MOF的合成过程的可持续性。我们专注于能源投入的替代形式和减少或替代不可持续的溶剂。因此，我们的目标是使用超声不仅可以降低合成温度，而且还可以研究合成条件对MOFs形式的相和结构的影响。预期在超声作用的影响下使用IL作为接头前体将导致动力学有利相的优选形成。

We propose a research project on the synthesis of novel porous coordination polymers (Metal-Organic Framework, MOF) from ionic liquids. The ionic liquid has a threefold role. It serves as a precursor for the MOF synthesis, as template and as solvent. In the second funding period, the focus will be on the template effect. For this, we will focus on the synthesis of liquid crystalline and chiral ionic liquids. The resulting new MOF materials will be characterized and the relation between structural variation of the IL and the structure of the MOF will be evaluated. Moreover, we want to optimize the synthesis of the MOF regarding the sustainability of the process. We focus on the alternative forms of energy input and the reduction or substitution of non-sustainable solvents. Thus, we aim to use sonification not only to reduce synthesis temperature but also to investigate the influence of the synthesis conditions on the phase and structure of the MOFs form. It is anticipated that the use of ILs as linker precursors under influence of sonification will result in the preferred formation of the kinetically-favored phase.