Tailor-Made Sequence-Controlled Polymer-Dye-Conjugates for Controlling Exciton Dynamics (A04)

该项目将开发一种序列定义的合成路线，以创建高度可定制的刚性大分子。新的合成策略将允许创建序列定义的棒状大分子，作为第一个例子，将用于理解和优化功能聚合物的能量转换的生物物理特性。这个项目与其他项目的不同之处在于，它所创造的功能是物理性质的，而不是化学性质的。然而，这种功能是通过化学控制来实现的，化学控制是为了精确地定位功能分子在空间中相对于刚性聚合物主链的位置。

This project will develop a sequence-defined synthesis route to create highly-tailorable rigid macromolecules. New synthetic strategies will allow the creation of sequence-defined rod-like macromolecules that will be used, as a first example, to understand and optimise the photophysical properties of functional polymers for energy conversion. This project is distinct from the others in that the functionality it creates is of a physical rather than chemical nature. However, this functionality is achieved by the chemical control developed to precisely locate functional molecules in space relative to the rigid polymer backbone.