New Functionalized and Patterned Surface Coatings via Cyclophane-Based Chemical Vapor Deposition (CVD) Polymerization (B03)

该项目涉及新型官能化环番的合成以及通过CVD聚合制备化学和拓扑控制的表面涂层。该项目旨在阐明三个主要结构元素的分子反应控制的作用：（i）CVD共聚物的主要序列，（ii）拓扑定义的聚合物结构，和（iii）在纳米纤维装饰的聚合物表面的分层控制手性。在合成方面，我们将通过CVD新的含氮杂环番使聚合物结构的范围多样化。将手性Phane型分子化学气相沉积聚合成手性和非手性介晶模板将进一步加深我们对多尺度手性的理解。

This Project deals with the synthesis of novel functionalised cyclophanes and the preparation of chemically and topologically controlled surface coatings via CVD polymerisation. The project seeks to elucidate the role of molecular reaction control for three major structural elements: (i) the primary sequence of CVD copolymers, (ii) topologically defined polymer architectures, and (iii) hierarchical controlled chirality in nanofibre-decorated polymer surfaces. Synthetically, we will diversify the range of polymer structures via CVD of novel nitrogen-containing heterocyclophanes. CVD polymerisation of chiral phane-type molecules into chiral and achiral mesogenic templates will further our understanding of multi-scale chirality.