Identification, Synthesis, and Application of Novel Enantiomerically Pure Titanocenes – Cyclic Voltammetry, Electrolysis, and Supramolecular Chemistry in Concert

我们将证明，cv筛选具有二茂钛配合物的超分子卤化物受体是一种有吸引力的预测方法，用于新型电化学或化学合成对映体纯二茂钛（III）配合物。我们将探讨这些配合物在一些催化相关反应中的性能。该方法也应该对其他复合物感兴趣。因此，它将扩展到其他钛（III）催化剂。研究其他低价金属配合物是本项目实现后的长期目标。

We will demonstrate that the CV-screening of supramolecular halide receptors with titanocene complexes is an attractive predictive method for novel electrochemical or chemical syntheses of enantiomerically pure titanocene(III) complexes. We will probe the performance of these complexes in a number of catalytic pertinent reactions. The method should be of interest for other complexes, too. Therefore, it will be expanded to other titanium(III) catalysts. Investigations with other low-valent metal complexes are long-term goals to be pursued after the realization of this project.