High Oxidation State and Related Chemistry of Organic Compounds of Palladium
High Oxidation State and Related Chemistry of Organic Compounds of Palladium
批准号:
DP0342842
负责人:
Prof Allan Canty
金额:
$30.96万
依托单位:
依托单位国家:
澳大利亚
项目类别:
Discovery Projects
财政年份:
2003
资助国家:
澳大利亚
项目状态:
已结题
起止时间:
2003-09-04 至 2008-06-30
中文摘要
钯能够形成含有钯碳键的化合物,这种类型的化合物出现在有机化合物的合成等应用中。这类钯化合物的基本化学将被探索,特别是钯的氧化态+IV,并重点关注与有机合成应用中发生的过程相关的反应。特别强调的是化学涉及磷化合物和不饱和的有机基团键合钯,并在化合物的基团,能够结合在一起离开钯作为有机化合物含有碳-氧键。
英文摘要
Palladium is able to form compounds containing palladium-carbon bonds, and compounds of this type occur in applications such as synthesis of organic compounds. The fundamental chemistry of this class of palladium compound is to be explored, in particular for the oxidation state +IV for palladium and with a focus on reactions that are relevant to processes occurring in organic synthesis applications. Particular emphasis is placed on chemistry involving phosphorus compounds and unsaturated organic groups bonded to palladium, and on compounds containing groups that are able to join together to depart from palladium as organic compounds containing carbon-oxygen bonds.
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