Electrochemical Formation of Nanomultilayer Structures of Manganese Oxides Intercalated with Photofunctional Molecules

我们成功地电沉积了光功能分子(卟啉、联吡啶配合物)、电子转移介体(甲基紫精)和具有大疏水基团的阳离子表面活性剂插层层状锰氧化物。光功能分子对层状氧化锰膜的光照射没有产生明显的光电流。另一方面，阳离子表面活性剂形成的有机相对苯二酚的催化氧化起到了反应场的作用。

We successfully electrodeposited layered manganese oxides intercalated with photofunctional molecules (porphyrin, ruthenium bipyridine comlex), electron transfer mediator (methyl viologen), and cationic surfactants with large hydrophobic moiety. Photo irradiation to the layered manganese oxide films with photofunctional molecules did not cause a significant photocurrent. On the other hand, cationic surfactants form an organic phase which functioned as a reaction field toward catalytic oxidation of hydroquinone.