Study on spontaneously-formed transparent conducting organic/inorganic nanocomposite materials

当真空蒸发金属与绿色电聚聚咔唑薄膜接触时，发生脱色反应(杂交反应)，得到新型透明导电聚合物薄膜。机理和化学分析表明，杂化反应是腐蚀反应和脱掺杂反应的结合。如果我们使用金属镓和它的芳香族化合物，我们发现杂交反应是在室温下通过它们与聚咔唑薄膜的接触而进行的。此外，使用可溶的聚卡里巴唑使溶液相的杂交反应成为可能，以产生透明导电油墨。

When vacuum evaporated metals were contacted on a green-colored electropolymerized polycarbazole film, decoloration reaction (hybridization reaction) occurred to give novel transparent conducting polymer films. The mechanistic and chemical analyses revealed that the hybridization reaction was the combination of corrosion reaction and dedoping reaction. If we use Ga metal and its arroys, the hybridization reaction was found to proceed at room temperatures simply by their contact with the polycarbazole film. Additionally, use of soluble polycaribazoles made possible the hybridization reaction in the solution phase to produce transparent conducting inks.