Research on Photofunctional Uranium(III) Complexes

该项目的目的之一是创建光功能铀（III）配合物。为实现这一目标，本研究主要集中在“光功能配体的评价与开发”和“铀（III）配合物合成方法的建立”两个方面。主要研究结果如下：（1）合成了新型光功能化三氮杂环壬烷（TACN）配体。(2)对目标铀（III）的模拟配合物铽（III）配合物进行了光物理表征，为配体的设计提供了有价值的指导。(3)发展了一条简便的铀（III）配合物的合成路线。

An aim of this project is creation of photofunctional uranium(III) complexes. In order to achieve the aim, the research was focused on "the evaluation and development of photofuncitonal ligands" and "the establishment of synthetic methods of uranium(III) complexes". The obtained results are as follows :(1) Novel photofunctionalized triazacyclononane (TACN) ligands were successfully synthesized.(2) The terbium(III) complexes, which are mock complexes of the aimed uranium(III), were photo-physically characterized and valuable guidelines on how to design the ligands were obtained.(3) A convenient synthetic route of uranium(III) complexes was developed.