DinActSi - Dinitrogen activation and functionalisation at silicon

我们将开发新的硅（II）化学方法，利用高活性的“蒙面”硅烯直接从N2合成有机氮化合物。该项目利用申请人在小分子活化方面的专业知识，并以东道国研究人员在硅（II）化学方面的最新进展为基础。有机氮化合物被用作肥料、药物、染料和聚合物。用氮气直接制备它们可以节约能源，减少浪费。到目前为止，研究工作主要集中在过渡金属化学上，但在这个项目中，我们将利用硅的化学特性来解决这个问题，硅既便宜又储量丰富。拟议的项目将使用合成化学来生产活性Si（II）化合物，这些化合物可以协调和激活N2。在此过程中，我们将开发新的催化相关工艺来从N2制备有机氮化合物。该研究员将获得成功的独立研究生涯所需的技能，并将接受包括计算化学和核磁共振在内的技术培训。研究人员将把电化学方面的专业知识传授给东道国。

We will develop new silicon(II) chemistry for the direct synthesis of organonitrogen compounds from N2 using highly reactive 'masked' silylenes.The project exploits the applicant's expertise in small-molecule activation and builds on recent advances in silicon(II) chemistry made by the host researcher. Organonitrogen compounds are used as fertilisers, drugs, dyes, and polymers. Their direct preparation from N2 would save energy and reduce waste.Work so far has focused on transition-metal chemistry, but in this project we will harness the chemistry of silicon - which is cheap and extremely abundant - to tackle this task. The proposed project will use synthetic chemistry to produce reactive Si(II) compounds that can coordinate and activate N2. In so doing, we will develop new catalytically relevant processes for preparing organonitrogen compounds from N2.The fellow will gain required skills for a successful independent research career, and will be trained in techniques including computational chemistry and NMR. The researcher will transfer expertise in electrochemistry to the host.