New Phosphorus- and Boron-Containing Allene Analogues for Small Molecule Activation and Catalysis

用于小分子活化和催化的新型含磷和含硼丙二烯类似物

基本信息

  • 批准号:
    NE/X00743X/1
  • 负责人:
  • 金额:
    $ 1.39万
  • 依托单位:
  • 依托单位国家:
    英国
  • 项目类别:
    Research Grant
  • 财政年份:
    2022
  • 资助国家:
    英国
  • 起止时间:
    2022 至 无数据
  • 项目状态:
    已结题

项目摘要

EPSRC : Vesela Zarkina : EP/R513209/1This project will develop new abundant-element systems for catalytically relevant chemistry. It will establish phosphorus/boron containing alternatives of a key class of compounds called allenes. The development of abundant-element chemistry, capable of the powerful synthetic transformations, traditionally enabled by precious metals, is key to reducing environmental damage and meeting the global economy requirements. This placement aims to overcome a central disadvantage of main-group element containing systems compared to precious metal ones: their limited coordination sites for chemical activation. This will be achieved by the synthesis of phosphorus/boron containing allenes which will be used for the chemical activation of small molecules such as hydrogen and carbon monoxide. This will provide fundamental knowledge required for further advances in metal-free catalysis and establish a new collaboration between two of the top main-group chemistry researchers leading the Stephan group at the University of Toronto and the Cowley group at the University of Edinburgh.
EPSRC:Vesela Zarkina:EP/R513209/1该项目将开发用于催化相关化学的新的丰度元素系统。它将建立含磷/硼的替代品的一个关键类别的化合物称为丙二烯。开发能够进行强大合成转化的丰富元素化学,传统上由贵金属实现,是减少环境破坏和满足全球经济需求的关键。这种放置旨在克服与贵金属相比含有主族元素的系统的核心缺点:它们用于化学活化的有限配位位点。这将通过合成含磷/硼的联烯来实现,所述联烯将用于小分子如氢和一氧化碳的化学活化。这将提供进一步发展无金属催化所需的基础知识,并在领导多伦多大学Stephan小组和爱丁堡大学Cowley小组的两名顶级主组化学研究人员之间建立新的合作。

项目成果

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Michael Cowley其他文献

Patient-related variables and restenosis after percutaneous transluminal coronary angioplasty--a report from the M-HEART Group.
经皮腔内冠状动脉成形术后患者相关变量和再狭窄——来自 M-HEART 小组的报告。
  • DOI:
    10.1016/0002-9149(90)90927-s
  • 发表时间:
    1990
  • 期刊:
  • 影响因子:
    0
  • 作者:
    Robert G. Macdonald;Mark A. Henderson;J. Hirshfeld;Sheldon H. Goldberg;Theodore Bass;G. Vetrovec;Michael Cowley;A. Taussig;H. Whitworth;James R. Margolis;James A. Hill;R. Jugo;C. J. Pepine
  • 通讯作者:
    C. J. Pepine
Role of percutaneous transluminal coronary angioplasty in the treatment of unstable angina. Report from the National Heart, Lung, and Blood Institute Percutaneous Transluminal Coronary Angioplasty and Coronary Artery Surgery Study Registries.
经皮冠状动脉腔内成形术在不稳定型心绞痛治疗中的作用。
  • DOI:
    10.1016/0002-9149(84)90766-5
  • 发表时间:
    1984
  • 期刊:
  • 影响因子:
    0
  • 作者:
    D. Faxon;K. Detre;Carolyn H. McCabe;Lloyd D. Fisher;David R. Holmes;Michael Cowley;M. Bourassa;M. V. Raden;Thomas J. Ryan
  • 通讯作者:
    Thomas J. Ryan
Mueller et al TIMI II Subgroup Analyses : Predictors of Early Events 1255 factors for early death in patients with AMI treated with thrombolytic therapy . The Thrombolysis in Myocardial Infarction ( TIMI ) phase
Mueller 等人的 TIMI II 亚组分析:早期事件的预测因素 1255 个导致接受溶栓治疗的 AMI 患者早期死亡的因素。
  • DOI:
    10.7326/0003-4819-113-6-423
  • 发表时间:
    2005
  • 期刊:
  • 影响因子:
    39.2
  • 作者:
    G. Knatterud;Kenneth Mann;Hiltrud S. Mueller;E. Passamani;David Stump;David Williams;Barry Zaret;J. Chesebro;Andrew Berke;Edwin G. Bovill;Frederick Feit;Joel Gore;L. Hillis;C. Lambrew;R. Leiboff;J. Markis;L. Offen;Craig M. Pratt;Scott Sharkey;George Sopko;M. Terrin;M. Weisfeldt;William Baker;Michael Cowley;Kenneth Kent;Edgar Lichstein;Thomas Robertson;Leonard Scherlis;Francis Klocke;D. DeMets;Valentin Fuster;T. Killip
  • 通讯作者:
    T. Killip
National heart, lung and blood institute registry report of complications of percutaneous transluminal coronary angioplasty
  • DOI:
    10.1016/0002-9149(81)90660-3
  • 发表时间:
    1981-02-01
  • 期刊:
  • 影响因子:
  • 作者:
    Gerald Dorros;Michael Cowley;John Simpson
  • 通讯作者:
    John Simpson
Effects of balloon size on immediate hemodynamic results of percutaneous mitral valvuloplasiy (PMV) in the M-heart registry
  • DOI:
    10.1016/0735-1097(90)91889-3
  • 发表时间:
    1990-02-01
  • 期刊:
  • 影响因子:
  • 作者:
    Howard C. Hermmann;J.Patrick Kleaveland;James A. Hill;Michael Cowley;Sheldon Goldberg;Steve Heilbrunn;John W. Hirshfeld;Charles R. Lambert;James R. Margolis;Jose C. Martin;Michael A. Nocero;George Vetrovec;Hall B. Whitworth;Andrew Zalewski;Carl J. Pepine
  • 通讯作者:
    Carl J. Pepine

Michael Cowley的其他文献

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{{ truncateString('Michael Cowley', 18)}}的其他基金

DinActSi - Dinitrogen activation and functionalisation at silicon
DinActSi - 硅上的二氮活化和功能化
  • 批准号:
    EP/X025594/1
  • 财政年份:
    2023
  • 资助金额:
    $ 1.39万
  • 项目类别:
    Fellowship

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逐步扩维法合成含磷和硼原子的笼状化合物
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