Synthesis beyond the redox-active tetrathiafulvalene (TTF) molecule: From a topological control in TTF-based macrocycles, towards functional s

功能化的TTF是富含pi电子的氧化还原活性积木，非常重要的是，它对许多合成转化都是稳定的。事实上，TTF体系具有广泛的应用，从分子有机金属的固态导电和磁性，到涉及TTF衍生物的可逆氧化还原、分子间电荷转移和氢键性质的分子/超分子体系。该应用程序通过为四个成本伙伴的访问提供旅费、消耗品和生活费来支持成本D31网络的活动。这里提出的研究项目的目的是为了将TTF物种合并到基于噻吩基的分子和大分子中。目标材料是电子设备中的潜在元件，如场效应晶体管、磁铁和光伏。

Functionalised TTFs are pi-electron rich redox-active building blocks which, quite importantly, are stable to many synthetic transformations. In fact, a great variety of applications can be associated with the TTF systems, ranging from solid state electroconducting and magnetic properties of molecular organic metals to molecular/supramolecular systems involving reversible redox, intermolecular charge-transfer and hydrogen-bonding properties of TTF derivatives. This application supports the activities of a COST D31 network by providing funding for travel, consumables and subsistence for visits from four of the COST partners. The aims of the research projects presented here entertain a general theme for incorporating TTF species into thiophene based molecules and macromolecules. The target materials are potential components in electronic devices, such as field effect transistors, magnets and photovoltaics.