课题基金 / 基金详情

Phosphorus-based ionic liquids and ligands for catalysis

Phosphorus-based ionic liquids and ligands for catalysis
磷基离子液体和催化配体
批准号:
354777-2007
负责人:
Alper, Howard
金额:
$5.46万
依托单位:
依托单位国家:
加拿大
项目类别:
Collaborative Research and Development Grants
财政年份:
2008
资助国家:
加拿大
项目状态:
已结题
起止时间:
2008-01-01 至 2009-12-31

项目摘要

项目成果

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中文摘要
翻译
过渡金属催化的反应对于许多工业化过程具有相当大的价值。本项目主要研究了膦基离子液体和膦基液体在金属催化羰基化、氧化、环羰基化以及氧化和还原羰基化反应中的应用。环境友好的离子液体的使用,以及进行许多原子经济性反应,提供了一种绿色科学方法,以催化潜在价值的商品,石化,聚合物和制药工业。发现用于金属催化反应的有效膦配体可以具有显著的商业价值。
英文摘要
Transition metal catalyzed reactions are of considerable value for a number of industrialized processes. This project is concerned with the application of phosphonium-based ionic liquids and phosphine liquids to metal catalized carbonylation, oxidation, cyclocarbonylation, as well as oxidative and reductive carbonylation reactions. The use of environmentally attractive ionic liquids, as well as conducting a number of atom economy reactions, provides a green science approach to catalysis of potential value to the commodity, petrochemical, polymer, and pharmaceutical industries. Discovering effective phosphine ligands for metal catalyzed reactions, can have significant commercial value.
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Organic chemistry catalyzed by transition metal complexes
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Organic chemistry catalyzed by transition metal complexes
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