Modeling the Fabrication of Functional Polymeric Materials by Spinodal Decomposition

该研究计划是申请人正在进行的研究的一部分，该研究是通过数学建模和计算机模拟在聚合物溶液和混合物中进行相分离（spinodal分解）。相分离聚合物溶液和共混物的应用包括：(1)用于分离过程的聚合物膜，(2)用于光电器件和智能窗口的聚合物分散液晶膜，(3)用于需要卓越机械性能的工程聚合物复合材料，以及(4)聚合物微电子电路和电阻。这项研究计划的总体目标是对聚合物溶液和共混物在进行相分离（spinodal分解）以制造功能聚合物材料时的形态演变有一个基本的了解。本研究计划的具体目标是：(1)模拟、模拟和表征存在温度和浓度梯度的表面诱导相分离的聚合物溶液和共混物的形态；(2)模拟、模拟和表征在相图的亚稳和不稳定区域连续淬火的聚合物溶液和共混物的形态；(3)模拟；模拟和表征聚合物溶液和共混物在温度和浓度梯度存在下进行压力诱导相分离的形态。温度和浓度梯度通常发生在聚合物溶液和共混加工过程中，以制造功能聚合物材料。

This proposed research program is part of the ongoing research that the applicant is pursuing on phase separation (spinodal decomposition) in polymer solutions and blends through mathematical modeling and computer simulation. Applications of phase separated polymer solutions and blends are found in: (1) polymeric membranes for separation processes, (2) polymer dispersed liquid crystal films for electro-optical devices and smart windows, (3) engineering polymer composite materials for purposes that require superior mechanical properties, and (4) polymeric microelectronic circuits and resists. The overall objective of this proposed research program is to develop a fundamental understanding of the morphological evolution of polymer solutions and blends undergoing phase separation (spinodal decomposition) to fabricate functional polymeric materials. The specific objectives are of this research proposal: (1) to model, simulate and characterize the morphology of polymer solutions and blends undergoing surface-induced phase separation in the presence of temperature and concentration gradients, (2) to model, simulate and characterize the morphology of polymer solutions and blends undergoing sequential quenching into the metastable and unstable regions of the phase diagram, and (3) to model, simulate and characterize the morphology of polymer solutions and blends undergoing pressure-induced phase separation in the presence of temperature and concentration gradients. Temperature and concentration gradients typically occur during polymer solutions and blends processing to fabricate functional polymeric materials.