Pd(II)-catalyzed ortho arylation of 2-arylbenzothiazoles with aryl iodides via benzothiazole-directed C-H activation.
Pd(II)-catalyzed ortho arylation of 2-arylbenzothiazoles with aryl iodides via benzothiazole-directed C-H activation.
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Pd(II)催化2-芳基苯并噻唑与芳基碘化物通过苯并噻唑引导的C–H活化进行邻位芳基化
DOI：
10.1016/j.jorganchem.2012.03.030
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发表时间：
2012-07-15
影响因子：
2.3
通讯作者：
Peng Y
中科院分区：
文献类型：
--
作者：
Ding Q;Ji H;Wang D;Lin Y;Yu W;Peng Y
介绍了一种新的高效的2-芳基苯并噻唑的C-H活化芳基化反应方法。所需的CAR-CAR键的形成具有良好的官能团耐受性和较高的区域选择性。描述了2-芳基苯并噻唑的芳基化反应机理。介绍了一种新的高效的2-芳基苯并噻唑的C-H活化芳基化反应方法。所需的CAR-CAR键的形成具有良好的官能团耐受性和较高的区域选择性。描述了2-芳基苯并噻唑的芳基化反应机理。►描述了2-芳基苯并噻唑通过钯催化的C-H活化的新型芳基化反应。►-CAR键的形成效率高，官能团耐受性好，区域选择性高。描述了►提出的2-芳基苯并噻唑的芳基化反应机理。
A novel and efficient method for the arylation of 2-arylbenzothiazoles is described via C–H activation. The desired CAr–CAr bond formation proceeded efficiently with good functional-group tolerance and high regioselectivity. Proposed mechanism for the arylation of 2-arylbenzothiazole is depicted. A novel and efficient method for the arylation of 2-arylbenzothiazoles is described via C–H activation. The desired CAr–CAr bond formation proceeded efficiently with good functional-group tolerance and high regioselectivity. Proposed mechanism for the arylation of 2-arylbenzothiazole is depicted. ► Novel arylation of 2-arylbenzothiazoles is described via palladium-catalyzed C–H activation. ► CAr–CAr bond formation proceeded efficiently with good functional-group tolerance and high regioselectivity. ► Proposed mechanism for the arylation of 2-arylbenzothiazole is depicted.
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影响因子：
16.6
作者：
Chen, Xiao;Engle, Keary M.;Wang, Dong-Hui;Yu, Jin-Quan
通讯作者：
Yu, Jin-Quan
影响因子：
9.8
作者：
Ding, Qiuping;Cao, Banpeng;Peng, Yi-Yuan
通讯作者：
Peng, Yi-Yuan
影响因子：
18.3
作者：
Daugulis O;Do HQ;Shabashov D
通讯作者：
Shabashov D
影响因子：
1.8
作者：
Ding, Qiuping;Liu, Xianjin;Peng, Yiyuan
通讯作者：
Peng, Yiyuan
影响因子：
5.2
作者：
Canivet, Jerome;Yamaguchi, Junichiro;Itami, Kenichiro
通讯作者：
Itami, Kenichiro