A palladium nanoparticle-nanomicelle combination for the stereoselective semihydrogenation of alkynes in water at room temperature.

A palladium nanoparticle-nanomicelle combination for the stereoselective semihydrogenation of alkynes in water at room temperature.
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DOI:
10.1002/anie.201407723
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发表时间:
2014-12-15
影响因子:
16.6
通讯作者:
Lipshutz, Bruce H.
Lipshutz, Bruce H.
中科院分区:
化学1区
文献类型:
--
作者:
Slack, Eric D.;Gabriel, Christopher M.;Lipshutz, Bruce H.

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Interactions between palladium nanoparticles and nanomicelles containing in situ-generated hydrogen and an alkyne lead to high yields of product Z-alkenes. These reactions are general, take place in water at ambient temperatures, and offer recycling of the aqueous reaction mixture along with low overall E Factors.
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