Above 1% efficiency of a ferroelectric solar cell based on the Pb(Zr,Ti)O3 film

Above 1% efficiency of a ferroelectric solar cell based on the Pb(Zr,Ti)O3 film
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以上%201%%20效率%20of%20a%20铁电%20solar%20cell%20based%20on%20the%20Pb(Zr,Ti)O3%20film

DOI:
10.1039/c3ta13724d
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发表时间:
2014
影响因子:
--
通讯作者:
Hao, Jianhua
Hao, Jianhua
中科院分区:
--
文献类型:
--
作者:
zheng,fg;Y. Xin;huang,w;J. X. Zhang;Hao, Jianhua

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在In 2 O3:Sn(ITO)玻璃上制备了带隙为3.6 eV的Pb(Zr,Ti)O3(PZT)薄膜,然后在PZT/ITO/玻璃上沉积了带隙为1.8 eV的非晶硅(a-Si)薄膜。Ag/a-Si/PZT/ITO/glass样品的短路电流为2.56 mA cm-2,约为Pt/PZT/ITO/glass样品的50倍。a-Si薄膜的能级与PZT薄膜的能级匹配良好,有利于紫外-可见光诱导电荷在Ag/a-Si/PZT/ITO/glass样品中的输运。光伏输出可以通过改变a-Si膜的掺杂类型来调节,并且在具有n型a-Si膜(磷掺杂)的PZT膜中测得最大光电转换效率高达1.25%。
Pb(Zr,Ti)O3 (PZT) film with a band gap of 3.6 eV was prepared on In2O3:Sn (ITO) coated glass, and then an amorphous silicon (a-Si) film with a narrow band gap of 1.8 eV was deposited on the PZT/ITO/glass. The short-circuit current of Ag/a-Si/PZT/ITO/glass sample is 2.56 mA cm−2, about 50 times greater than that of Pt/PZT/ITO/glass sample. The energy level of the a-Si film is well matched with that of PZT film, which is beneficial to the transport of UV-visible light-induced charges in the Ag/a-Si/PZT/ITO/glass sample. The photovoltaic output can be tuned by changing the dopant type of the a-Si film, and the maximum photoelectric conversion efficiency is measured to be up to 1.25% in the PZT film with an n-type a-Si film (phosphorus doped).
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