Microstructure evolution and properties of rapidly solidified Au-20Sn eutectic solder prepared by single-roll technology

Microstructure evolution and properties of rapidly solidified Au-20Sn eutectic solder prepared by single-roll technology
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单辊技术制备快凝Au-20Sn共晶焊料的组织演变及性能

DOI:
10.1016/j.jallcom.2018.12.073
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发表时间:
2019-04
影响因子:
6.2
通讯作者:
Shangyu Huang
Shangyu Huang
中科院分区:
材料科学2区
文献类型:
--
作者:
Shengfa Liu;Dongxiao Zhang;Jieran Xiong;Chen Chen;Tianjie Song;Li Liu;Shangyu Huang

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目前芯片级Au-Sn焊料生产工艺十分复杂,为简化工艺同时提高焊料质量,采用单辊快速凝固技术制备Au-20Sn焊带。研究了焊料的微观结构演变、成分分布、相组成、熔化特性、润湿性和机械性能。快速凝固的Au-20Sn焊料合金由少量初生δ'-Au5Sn枝晶和共晶结构(δ'-Au5Sn+δ-AuSn)组成。退火过程中组织细化,成分分布均匀,没有新相形成。随着Sn元素从δ'-Au5Sn相扩散到δ-AuSn相中,δ'-Au5Sn相发生分解,δ-AuSn相长大并分布在基体中。轧制后,δ-AuSn相沿薄带的伸长方向伸长,元素进一步偏析。最终,与铸轧Au-20Sn焊料相比,熔化范围更窄,焊点的润湿性和剪切强度得到改善。
The current chip-level Au-Sn solder production process is very complex, to simplify the process while improving the quality of the solder, Au-20Sn solder ribbon was prepared by single-roll rapid solidification technology. The microstructure evolution, composition distribution, phase composition, melting characteristics, wettability and mechanical properties of the solder were studied. The rapidly solidified Au-20Sn solder alloy consisted of a small amount of primary ζ′-Au5Sn dendrites and eutectic structure (ζ′-Au5Sn+δ-AuSn). The microstructure was refined and the components were evenly distributed, while no new phase was formed during the annealing. With Sn element diffused into the δ-AuSn phase from the ζ′-Au5Sn phase, the ζ′-Au5Sn phase was decomposed and the δ-AuSn phase grew up and distributed in the matrix. After rolling, the δ-AuSn phase was elongated along the elongation direction of the ribbon, and the elements were further segregated. Ultimately, compared to the cast-rolling Au-20Sn solder, the melting range was narrower, and the wettability and the shear strength of the solder joint improved.
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