An Investigation on a Crystalline-Silicon Solar Cell with Black Silicon Layer at the Rear.

An Investigation on a Crystalline-Silicon Solar Cell with Black Silicon Layer at the Rear.
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背面黑硅层晶体硅太阳能电池的研究

DOI:
10.1186/s11671-017-2388-y
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发表时间:
2017-12-15
影响因子:
--
通讯作者:
Lu M
Lu M
中科院分区:
材料科学3区
文献类型:
--
作者:
Zhou ZQ;Hu F;Zhou WJ;Chen HY;Ma L;Zhang C;Lu M

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为了研制具有亚带隙光伏响应的c-Si(c-Si)太阳电池,研究了背面有黑色Si(b-Si)层的c-Si(c-Si)太阳电池。采用化学腐蚀法制备了单晶硅。C-Si太阳电池的性能远好于类似结构但没有b-Si的c-Si太阳电池,效率相对提高27.7%。这一发现很有趣,因为b-Si具有很大的比表面积,这可能会导致高表面复合和太阳能电池性能退化。C-Si太阳电池的后部形成了梯度带隙,其后部是b-Si层。这种梯度带隙倾向于将自由电子从背面排出,从而降低了b-Si处电子-空穴复合的几率,并提高了c-Si太阳电池的性能。
Crystalline-Si (c-Si) solar cell with black Si (b-Si) layer at the rear was studied in order to develop c-Si solar cell with sub-band gap photovoltaic response. The b-Si was made by chemical etching. The c-Si solar cell with b-Si at the rear was found to perform far better than that of similar structure but with no b-Si at the rear, with the efficiency being increased relatively by 27.7%. This finding was interesting as b-Si had a large specific surface area, which could cause high surface recombination and degradation of solar cell performance. A graded band gap was found to form at the rear of the c-Si solar cell with b-Si layer at the rear. This graded band gap tended to expel free electrons away from the rear, thus reducing the probability of electron-hole recombination at b-Si and improving the performance of c-Si solar cell.
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发表时间: 2006-07-24
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