Rhodium-catalyzed acyloxy migration of propargylic esters in cycloadditions, inspiration from the recent "gold rush".
Rhodium-catalyzed acyloxy migration of propargylic esters in cycloadditions, inspiration from the recent "gold rush".
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DOI：
10.1039/c2cs35235d
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发表时间：
2012-12-07
影响因子：
46.2
通讯作者：
Tang W
中科院分区：
文献类型：
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作者：
Shu XZ;Shu D;Schienebeck CM;Tang W
Transition metal-catalyzed acyloxy migration of propargylic esters offers versatile entries to allene and vinyl carbene intermediates for various fascinating subsequent transformations. Most π-acidic metals (e.g. gold and platinum) are capable of facilitating these acyloxy migration events. However, very few of these processes involve redox chemistry, which are well-known for most other transition metals such as rhodium. The coupling of acyloxy migration of propargylic esters with oxidative addition, migratory insertion, and reductive elimination may lead to ample new opportunities for the design of new reactions. This tutorial review summarizes recent developments in Rh-catalyzed 1,3- and 1,2-acyloxy migration of propargylic esters in a number of cycloaddition reactions. Related Au- and Pt-catalyzed cycloadditions involving acyloxy migration are also discussed.
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DOI：
10.1039/c2cc17406e
发表时间：
2012-02-21
期刊：
Chemical communications (Cambridge, England)
影响因子：
--
作者：
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通讯作者：
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