Doping potassium ions in silver cyanide complexes for green luminescence.
Doping potassium ions in silver cyanide complexes for green luminescence.
复制标题
在氰化银络合物中掺杂钾离子以产生绿色发光。
DOI:
10.1039/c3dt53219d
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发表时间:
2014-02
影响因子:
4
通讯作者:
Huang, Kun-Lin
中科院分区:
文献类型:
--
作者:
Liu, Xi;Li, Lin;Yang, Yun-Zhi;Huang, Kun-Lin
Doping potassium ions in silver cyanide complexes leads to two heterometallic silver-potassium cyanide complexes, namely, [Me4N]2[KAg3(CN)6] (1) with a typical NaCl-type framework containing distinct ligand-unsupported argentophilic interactions, and [Ag3(H2O)3][K(CN)2]3 (2) with an unprecedented 3-D (4,4,6,6)-connected framework formed by unique [Ag3(H2O)3] clusters connecting concave-convex [K(CN)2] layers. The two complexes exhibit green luminescence, and the relationships between their structures and photoluminescence, as well as the regulating effect on the luminescence by doping of potassium ions are well investigated via density functional theory analysis.
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