Broadened negative thermal expansion operation-temperature window in antiperovskite Mn3Zn0.6Ge0.4N prepared by spark plasma sintering

Broadened negative thermal expansion operation-temperature window in antiperovskite Mn3Zn0.6Ge0.4N prepared by spark plasma sintering
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放电等离子烧结制备的反钙钛矿Mn3Zn0.6Ge0.4N扩大负热膨胀工作温度窗口

DOI:
10.1016/j.jallcom.2014.01.027
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发表时间:
2014-04
影响因子:
6.2
通讯作者:
Laifeng Li
Laifeng Li
中科院分区:
材料科学2区
文献类型:
--
作者:
Jie Tan;Rongjin Huang;Wen Li;Yemao Han;Laifeng Li

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Anti-perovskite manganese nitrides Mn3Zn0.6Ge0.4N with different crystallite size were prepared by spark plasma sintering (SPS) at different sintering temperatures. Their negative thermal expansion (NTE) properties were investigated. It was found that the width of NTE operation-temperature window (ΔT) broadens with decreasing crystallite size. Typically, a broad ΔTof 105 K was obtained in the compound Mn3Zn0.6Ge0.4N with average crystallite size of 54 nm sintered at 700 °C, of which the average linear thermal expansion coefficient was estimated to be −13.5 × 10−6K−1in the NTE operation-temperature window. This antiperovskite manganese nitride Mn3Zn0.6Ge0.4N with broadened ΔTaround room temperature is more useful for practical applications.
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