Fluorination of metal phthalocyanines: single-crystal growth, efficient N-channel organic field-effect transistors, and structure-property relationships.
Fluorination of metal phthalocyanines: single-crystal growth, efficient N-channel organic field-effect transistors, and structure-property relationships.
复制标题
DOI:
10.1038/srep07573
复制
发表时间:
2014-12-19
影响因子:
4.6
通讯作者:
Kloc C
中科院分区:
文献类型:
--
作者:
Jiang H;Ye J;Hu P;Wei F;Du K;Wang N;Ba T;Feng S;Kloc C
The fluorination of p-type metal phthalocyanines produces n-type semiconductors, allowing the design of organic electronic circuits that contain inexpensive heterojunctions made from chemically and thermally stable p- and n-type organic semiconductors. For the evaluation of close to intrinsic transport properties, high-quality centimeter-sized single crystals of F16CuPc, F16CoPc and F16ZnPc have been grown. New crystal structures of F16CuPc, F16CoPc and F16ZnPc have been determined. Organic single-crystal field-effect transistors have been fabricated to study the effects of the central metal atom on their charge transport properties. The F16ZnPc has the highest electron mobility (~1.1 cm2 V−1 s−1). Theoretical calculations indicate that the crystal structure and electronic structure of the central metal atom determine the transport properties of fluorinated metal phthalocyanines.
登录
查看更多内容
影响因子:
--
作者:
Jiang, Hui;Tan, Ke Jie;Kloc, Christian
通讯作者:
Kloc, Christian
影响因子:
5
作者:
Jiang, Hui;Kloc, Christian
通讯作者:
Kloc, Christian
DOI:
10.1007/s00339-008-5014-0
发表时间:
2009-04-01
影响因子:
2.7
作者:
Kloc, C.;Tan, K. J.;Xu, Y. P.
通讯作者:
Xu, Y. P.
影响因子:
15
作者:
de Oteyza, Dimas G.;Barrena, Esther;Dosch, Helmut
通讯作者:
Dosch, Helmut
影响因子:
3.2
作者:
Huang, Cheng;Katz, Howard E.;West, James E.
通讯作者:
West, James E.