Carbon electrode fabrication from pyrolyzed parylene C.

Carbon electrode fabrication from pyrolyzed parylene C.
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DOI:
10.1021/ac200885w
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发表时间:
2011-07-01
影响因子:
7.4
通讯作者:
Baker, Lane A.
Baker, Lane A.
中科院分区:
化学1区
文献类型:
--
作者:
Morton, Kirstin C.;Morris, Celeste A.;Derylo, Maksymilian A.;Thakar, Rahul;Baker, Lane A.

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碳电极与电化学检测联用已被广泛用于生物胺的研究。在本论文中,我们报道了由热解的对二甲苯C(PPC)薄膜制备的碳质电极的制备和表征。用一层绝缘的对二甲苯C膜掩蔽PPC涂层的吸管,制备了高深宽比的碳微电极。用电化学、光谱和电子显微镜对PPC薄膜电极进行了表征。这里描述的过程提供了一种制造薄膜碳电极的方法,这种电极可以被图案化并并行生产。这些电极类似于从热解光致抗蚀剂薄膜中提取的碳电极,但不需要旋涂或光刻,并且可以很容易地覆盖三维表面。
Carbon electrodes coupled with electrochemical detection have been used extensively for the investigation of biogenic amines. Herein we report the fabrication and characterization of carbonaceous electrodes prepared from pyrolyzed parylene C (PPC) films. High-aspect ratio carbonaceous microelectrodes have been prepared by masking PPC coated pipettes with an insulating parylene C film. PPC thin film electrodes were characterized electrochemically, spectroscopically, and with electron microscopy. The procedures described here offer a route to fabrication of thin film carbon electrodes that can be patterned and produced in parallel. These electrodes are similar to carbon electrodes derived from pyrolyzed photoresist films but do not require spin-coating or lithography and can readily coat three-dimensional surfaces.
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