Bias voltage dependence of superlubricity lifetime of hydrogenated amorphous carbon films in high vacuum

Bias voltage dependence of superlubricity lifetime of hydrogenated amorphous carbon films in high vacuum
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高真空中氢化非晶碳薄膜超润滑寿命的偏压依赖性

DOI:
10.1016/j.triboint.2017.08.020
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发表时间:
2018
影响因子:
6.2
通讯作者:
Xianrong Wang
Xianrong Wang
中科院分区:
工程技术1区
文献类型:
--
作者:
Longchen Cui;Hui Zhou;Kaifeng Zhang;Zhibin Lu;Xianrong Wang

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在不同偏置电压下,用磁控溅射法在Ar+C2H2混合气体中沉积了氢化非晶碳(a-C:H)薄膜。A-C:H薄膜的力学性能、拉曼光谱和高真空摩擦行为表明,在偏压为0、-50和−100V时沉积的薄膜为类聚合物碳膜,在−为150V时沉积的薄膜为类金刚石碳膜。随着偏压的增加,薄膜在高真空下的超润滑性寿命从10000次增加到28000次,摩擦系数∼为0.002。类金刚石薄膜的耐磨寿命为∼600次。PLC薄膜耐磨性的提高归功于PLC网络交联度的提高和薄膜致密性的提高。
We deposit hydrogenated amorphous carbon (a-C:H) films by magnetron sputtering of graphite in an Ar + C2H2 mixture at various bias voltages. The mechanical properties, Raman spectra, and high-vacuum frictional behaviors of the a-C:H films indicate that the films deposited at bias 0, –50, and −100 V are polymer-like carbon (PLC) films and the film deposited at −150 V is a diamond-like carbon (DLC) film. The lifetimes of superlubricity, with friction coefficient ∼0.002, of the PLC films in high-vacuum increase from 10000 to 28000 cycles with increasing bias, although the film thicknesses decrease. The DLC film's wear-life is ∼600 cycles. The enhanced wear-resistance in PLC films is attributed to improvement of the crosslinking degree of the PLC network and the film compactness.
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