Deep Eutectic Solvents and Multicomponent Reactions: Two Convergent Items to Green Chemistry Strategies.
Deep Eutectic Solvents and Multicomponent Reactions: Two Convergent Items to Green Chemistry Strategies.
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深层溶剂和多组分反应：两个收敛项降低了绿色化学策略。
DOI：
10.1002/open.202100137
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发表时间：
2021-08
期刊：
影响因子：
2.3
通讯作者：
Mingorance-Sánchez C
中科院分区：
文献类型：
--
作者：
Calvo-Flores FG;Mingorance-Sánchez C
绿色化学的亮点之一是开发对环境影响小的技术和程序。近年来，低共熔溶剂（DES）已成为传统有机溶剂的重要替代品。一段时间以来，离子液体引起了人们极大的兴趣，但它们已被DES取代，因为它们具有更容易的制备方法，更低的价格，其中许多是可生物降解的，并且与生物系统相容。此外，它们还显示出可调节的物理化学性质、高热稳定性、低挥发性和与水相容。本文综述了DES在有机合成中的应用，特别是反应介质在有机合成中的作用。低共熔溶剂是传统溶剂的一种有趣的替代品，既可以作为反应介质，也可以用于化学和相关科学中使用的许多工艺和技术。它们易于制备，用途广泛，其中许多可以从可再生资源中获得，并且可以针对特定工艺进行设计和调整。由于所有这些原因，近年来对它们进行了深入的研究，而且对它们的兴趣不断增加。本文回顾了一些最突出的应用程序，哪些是感兴趣的领域，可能是一个重点的应用程序在不久的将来。
One of the highlights of green chemistry is the development of techniques and procedures with low environmental impact. In the last years, deep eutectic solvents (DES) have become an important alternative to conventional organic solvents. For a period ionic liquids have provoked remarkable interest, but they have been displaced by DES because they show easier preparation methods, lower prices, many of them are biodegradable and compatible with biological systems. In addition, they show adjustable physicochemical properties, high thermal stability, low volatility and are compatible with water. In this paper is reviewed the state of the art of the use of DES paying special attention to the role of reaction media in organic synthesis. Deep eutectic solvents are an interesting alternative to conventional solvents, both as a reaction medium and for many processes and technologies used in chemistry and related sciences. They are easily prepared, versatile, many of them can be obtained from renewable sources and can be designed and adapted for specific processes. For all these reasons, they have been studied intensively in recent years and their interest is constantly growing. This paper reviews some of the most prominent applications and which are the fields of interest that may be a focus of applications in the near future.
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影响因子：
4.3
作者：
Abbott, AP;Capper, G;Rasheed, RK
通讯作者：
Rasheed, RK
影响因子：
4.2
作者：
Azizi, Najmedin;Khajeh, Meysam;Alipour, Masoumeh
通讯作者：
Alipour, Masoumeh
DOI：
10.1016/j.jarmap.2016.03.003
发表时间：
2016-09-01
影响因子：
3.9
作者：
Bakirtzi, Christina;Triantafyllidou, Katerina;Makris, Dimitris P.
通讯作者：
Makris, Dimitris P.
影响因子：
15
作者：
Abbott, AP;Boothby, D;Rasheed, RK
通讯作者：
Rasheed, RK
深层溶剂和多组分反应：两个收敛项降低了绿色化学策略。
影响因子：
2.3
作者：
Calvo-Flores FG;Mingorance-Sánchez C
通讯作者：
Mingorance-Sánchez C