From the bottom up: dimensional control and characterization in molecular monolayers.

From the bottom up: dimensional control and characterization in molecular monolayers.
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DOI:
10.1039/c2cs35365b
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发表时间:
2013-04-07
影响因子:
46.2
通讯作者:
Weiss PS
Weiss PS
中科院分区:
化学1区
文献类型:
--
作者:
Claridge SA;Liao WS;Thomas JC;Zhao Y;Cao HH;Cheunkar S;Serino AC;Andrews AM;Weiss PS

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自组装单分子膜是一类独特的纳米结构材料,其性质取决于其分子晶格结构以及与基底和环境的界面。与其他纳米结构材料一样,缺陷和维度在单分子膜的物理、化学和生物学性质中起着重要作用。在这篇综述中,我们讨论了单层结构,从表面(二维)到单分子(零维),重点是每种类型的结构的应用程序,和技术,使表征单层的物理性质下降到单分子尺度。
Self-assembled monolayers are a unique class of nanostructured materials, with properties determined by their molecular lattice structures, as well as the interfaces with their substrates and environments. As with other nanostructured materials, defects and dimensionality play important roles in the physical, chemical, and biological properties of the monolayers. In this review, we discuss monolayer structures ranging from surfaces (two-dimensional) down to single molecules (zero-dimensional), with a focus on applications of each type of structure, and on techniques that enable characterization of monolayer physical properties down to the single-molecule scale.
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