Aerobic Coupling Reactions Catalyzed by Binuclear Copper Compounds

双核铜化合物催化的有氧偶联反应

• 批准号: 8419211
• 负责人: Phooi Lim
• 金额: $ 22.05万
• 依托单位: North Carolina State University
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 1985
• 资助国家: 美国
• 起止时间: 1985-09-01 至 1989-02-28
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=8419211&HistoricalAwards=false
• 关键词: Aerobic; Coupling; Reactions; Catalyzed; Binuclear

Aerobic coupling reactions which are induced catalytically by binuclear copper compounds will be investigated to uncover additional couplig systems which are of commercial and scientific interest in synthesis and separation processes, and to fill in existing gaps in the understanding of existing aerobic coupling reactions. New combinations of catalysts, ligands, and solvents will be sought which are more effective than those presently known. In addition, the possibility will be examined that surfactants and cross-coupling reactions between different compounds may greatly enhance the engineering potential of aerobic coupling reactions, and the effect of ultraviolet light on these reactions will be determined. Finally, polymer-supported catalysts with binuclear structures will be designed to support specific coupling reactions. These new systems may lead to novel processes for the removal of toxic and hazardous organic compounds from aqueous solutions and for the recovery of certain types of biochemical compounds.

双核催化诱导的好氧偶联反应 将研究铜化合物，以发现更多的耦合。 在合成方面具有商业和科学意义的系统 和分离进程，并填补 了解现有的有氧耦合反应。 新组合 催化剂、配体和溶剂的混合物将被寻求， 比目前已知的更有效。 此外， 将检查表面活性剂和交叉偶联反应之间 不同的化合物可以极大地提高 好氧耦合反应，以及紫外光对 将确定这些反应。 最后，聚合物支撑的 具有双核结构的催化剂将被设计成支持 特定的偶联反应。 这些新系统可能会导致新的 用于从废水中去除有毒和有害有机化合物的方法， 水溶液和用于回收某些类型的生化 化合物.