Presidential Young Investigator Award/Transmission of Stereochemical Information

总统青年研究员奖/立体化学信息传输

• 批准号: 8857812
• 负责人: Jay Siegel
• 金额: $ 31.2万
• 依托单位: University of California-San Diego
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 1988
• 资助国家: 美国
• 起止时间: 1988-07-15 至 1993-12-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=8857812&HistoricalAwards=false
• 关键词: Presidential; Young; Investigator; Award; Transmission

This Presidential Young Investigator Award given in the Organic and Macromolecular Chemistry Program provides support for the work of Dr. Jay Siegel, University of California, San Diego. This work is focused on the broad topic of molecular recognition. Molecular recognition is at the heart of all chemical interactions and reactions. Its details will explain not only the complicated interactions of biomolecules, but also will allow the design of specific catalytic processes and important new chemical reactions. Conformational analyses of helical substructures in both monomers and polymers will be undertaken. These may lead to isosteric structures having different electronic and chromophoric properties. Such structures have potential applications as semiconductors, molecular solenoids, and non-linear optical materials. In addition, organometallic arene-metal complexes will be prepared to study metal-ligand dynamics, metal-centered reactivity, and bond fixation in the arenes.

这个总统青年研究者奖在有机 和高分子化学计划提供支持， 杰·西格尔博士的工作，加州大学圣地亚哥分校。 这项工作的重点是广泛的主题分子 识别.分子识别是所有 化学反应和反应。它的细节将解释 不仅是生物分子之间复杂的相互作用， 将允许设计特定的催化过程， 重要的新化学反应。 螺旋亚结构的构象分析 单体和聚合物。这些可能导致 具有不同电子和电子结构的电子等排结构 发色性质这种结构具有潜力 应用如半导体、分子筛、 非线性光学材料此外，有机金属 芳烃-金属配合物的制备是研究金属配体 动力学，金属为中心的反应，并在键固定 芳烃。