Stereochemistry of Nanoscale Molecules

纳米级分子的立体化学

• 批准号: 9904275
• 负责人: Jay Siegel
• 金额: $ 46.5万
• 依托单位: University of California-San Diego
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 1999
• 资助国家: 美国
• 起止时间: 1999-08-01 至 2002-07-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=9904275&HistoricalAwards=false
• 关键词: Stereochemistry; Nanoscale; Molecules

This project explores the synthesis of nanoscale molecules and the study of their stereochemistry. Three nanoscale molecular morphologies will be studied: stem-palmate clusters, entwined networks, and shells and surfaces. Experimental, theoretical and computational chemistry will brought to bear on the elucidation of nanoscale molecules with these morphologies, and new synthetic routes will be developed to synthesize chemical structures chosen to expand and mature the area of nanoscale molecular design.With this Award, the Organic and Macromolecular Chemistry Program continues support for the research of Professor Jay Siegel of the University of California - San Diego. Professor Siegel and co-workers are exploring the nature of new kinds of organic matter that bridge the gap between the microscopic and macroscopic. These molecular assemblies will be subject to rational and deliberate design principles based on fundamental organic chemistry, and their properties will be explored using a variety of techniques. With this knowledge, the ability to create very large molecules with specific properties and purposes may soon be realized.

该项目探索纳米级分子的合成及其立体化学的研究。 三个纳米级的分子形态将被研究：茎棕榈酸簇，包封网络，壳和表面。 实验，理论和计算化学将带来承担与这些形态的纳米级分子的阐明，并将开发新的合成路线，以合成选择扩大和成熟的纳米级分子设计领域的化学结构。有了这个奖项，有机和高分子化学计划继续支持教授的研究杰伊西格尔的加州-圣地亚哥大学。 西格尔教授和他的同事们正在探索新型有机物的性质，这种有机物是微观和宏观之间差距的桥梁。 这些分子组装将受到基于基础有机化学的合理和故意的设计原则，并将使用各种技术探索它们的特性。 有了这些知识，创造具有特定性质和目的的超大分子的能力可能很快就会实现。