Purchase of a Solid State Nuclear Magnetic Resonance Spectrometer

现代固态核磁共振（NMR） 光谱学为化学家提供了一种最有力的工具 可用于物理和化学性质的研究 的材料。 结构和动力学基础知识 材料的多样性，如生物聚合物，树脂，煤炭， 液晶可通过固态NMR技术获得。 固体核磁共振研究通常是对那些已经进行的研究的补充 使用溶液核磁共振和X射线分析。 进入固态 核磁共振正迅速成为化学家进行 前沿研究 该奖项由化学仪器计划和 仪器和仪表发展计划将有助于 普林斯顿大学化学系 一种高场核磁共振光谱仪， 固态NMR研究。 研究领域将是 通过收购增强了以下内容： 1)固体核磁共振中的脉冲形状效应 2)杂环化学研究 3)六芳基乙烷的固态结构研究 4)有机插层化合物作为模型的 金属配合物与无机表面的反应 5)氧化物结合金属络合物催化剂的结构研究 6)膜结合型合成树脂的结构和动力学研究 金属卟 7)肌动蛋白复合物的结构和动力学。

Modern solid-state Nuclear Magnetic Resonance (NMR) spectroscopy offers the chemist one of the most powerful tools available for the study of the physical and chemical properties of materials. Fundamental knowledge of structure and dynamics of materials as diverse as biopolymers, resins, coals, and liquid crystals is accessible by solid-state NMR techniques. Solid-state NMR studies often complement those carried out using solution NMR and X-ray analysis. Access to solid-state NMR is rapidly becoming essential to chemists carrying out frontier research. This award from the Chemical Instrumentation Program and the Instrumentation and Instrument Development Program will help the Department of Chemistry at Princeton University to acquire a high-field NMR spectrometer suitable for carrying out solid-state NMR studies. The areas of research that will be enhanced by the acquisition include the following: 1) Pulse shape effects in solid-state NMR 2) Studies in heterocyclic chemistry 3) Solid-state structural studies of hexaarylethanes 4) Organometallic intercalation compounds as models for the reactions of metal complexes with inorganic surfaces 5) Structural studies on oxide-bound metal complex catalysts 6) Structural and dynamic studies of membrane-bound synthetic metalloporphyrins 7) Structure and dynamics of the profilin:actin complex.