Mechanisms of Transition Metal-Catalyzed Reactions in Hydrocarbons

在本项目（“过渡金属催化的 碳氢化合物中的反应”），由 化学系有机动力学计划与 材料研究部聚合物计划， 罗伯特H.格拉布斯教授的化学系在 加州理工学院将研究这些机制 用于有机金属试剂的聚合物合成。 的 项目旨在提供基本技术和 机械的理解，需要开发新的 过去几年发现的催化剂， 合成大分子系统。 这是一个基础性和多学科的项目， scope.正在调查的主要问题涉及广泛 进一步阐述了“ROMP”聚合物，并将包括 阴离子引发，大分子单体合成，立构规整度 控制，光化学引发，钌化学 水介质，各种钛和锆系统，以及双 施洛克启动器。

In this project ("Mechanisms of Transition Metal- Catalyzed Reactions in Hydrocarbons"), which is jointly supported by the Organic Dynamics Program of the Chemistry Division and the Polymers Program of the Division of Materials Research, Professor Robert H.Grubbs of the Chemistry Department at the California Institute of Technology will study the mechanisms for polymer synthesis with organometallic reagents. The project is designed to provide the fundamental techniques and the mechanistic understanding that is required to exploit new catalysts that have been uncovered over the past few years for synthesizing macromolecular systems. This is project is fundamental and multidisciplinary in its scope. The major topics being investigated deal extensively with further elaboration of "ROMP" polymers and will include studies on anionic initiation, macromer synthesis, tacticity control, photochemical initiation, ruthenium chemistry in aqueous media, various titanium and zirconium systems, and dual Schrock initiators.