U.S.-Hungary Research on Chemical Reactions Catalyzed by Organometallic Reagents in Aqueous Solutions

美匈关于有机金属试剂在水溶液中催化化学反应的研究

• 批准号: 9008227
• 负责人: Donald Darensbourg
• 金额: $ 3.84万
• 依托单位: Texas A&M University
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 1990
• 资助国家: 美国
• 起止时间: 1990-08-01 至 1993-07-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=9008227&HistoricalAwards=false
• 关键词: U.S.; Hungary; Research; Chemical; Reactions

The primary objective of this U.S.-Hungary research project between Dr. Donald Darensbourg of Texas A&M University and Dr. F. Joo of Kossuth Lajos University, Debrecen, is to study the use of aqueous solutions as a media for reactions catalyzed by organometallic complexes. The researchers will use transition metal complexes with sulphonated tertiary phosphine ligands in these efforts. Their examination will focus on ligand exchange processes, hydrogen transfer reactions and interaction of carbon oxides, especially carbon dioxide. Results should contribute to our understanding of the effects one may expect when water is used as a solvent in organometallic catalytic processes. This project in organometallic chemistry fulfills the program objective of advancing scientific knowledge by enabling leading experts in the United States and Eastern Europe to combine complementary talents and pool research resources in areas of strong mutual interest and competence.

这项由德克萨斯农工大学的Donald Darensburg博士和德布勒森Kossuth Lajos大学的F.Joo博士合作的美国-匈牙利研究项目的主要目标是研究将水溶液用作有机金属络合物催化反应的介质。在这些工作中，研究人员将使用过渡金属与磺化的叔膦配体的络合物。他们的研究将集中在配体交换过程、氢转移反应和二氧化碳，特别是二氧化碳之间的相互作用。结果应该有助于我们理解在有机金属催化过程中使用水作为溶剂时可能产生的影响。这一有机金属化学项目通过使美国和东欧的顶尖专家能够将互补的人才结合在一起，并在相互感兴趣和能力很强的领域汇集研究资源，实现了促进科学知识的计划目标。