Electronic and Chemical Interactions of Buckminster Fullerene

巴克明斯特富勒烯的电子和化学相互作用

• 批准号: 9108419
• 负责人: John Weaver
• 金额: $ 62.59万
• 依托单位: University of Minnesota-Twin Cities
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 1991
• 资助国家: 美国
• 起止时间: 1991-07-15 至 1997-12-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=9108419&HistoricalAwards=false
• 关键词: Electronic; Chemical; Interactions; Buckminster; Fullerene

A systematic study of the electronic structure and reactivity of a new class of molecular carbon clusters (fullerenes) is proposed. The program is aimed at the following issues: investigating the electronic energy level distributions for isolated and derivatized fullerene molecules, studying the changes in occupied and empty electronic states due to solid-state formation, with an emphasis on energy band formation, surface and interfacial studies of bond formation and stability of Fullerenes with metal and semiconductor adatoms and overlayers; catalysis, and photon- and electron- enhanced oxidation.

系统地研究了一种新的金属离子的电子结构和反应活性， 提出了一类新的分子碳簇（富勒烯）。 该方案旨在解决以下问题： 孤立和衍生的电子能级分布 富勒烯分子，研究被占据和空 由于固态形成的电子状态，重点是 键的能带形成、表面和界面研究 富勒烯与金属和半导体的形成和稳定性 吸附原子和覆盖层;催化，光子和电子- 增强氧化。